Browsing by Author "Nishant Singh"

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Evaluation and comparison of stress distribution around periodontally compromised mobile teeth splinted with different materials: Three-dimensional finite element analysis
(Wolters Kluwer Medknow Publications, 2019) Farhan Durrani; Arpit Galohda; Sanjay Rai; Nishant Singh; Rati Verma; Dhananjay Yadav; S.M. Karthickraj
Background: Progressive attachment loss around the teeth because of periodontal disease can result in increased tooth mobility. This adversely affects patient's comfort, function, and esthetics. Periodontal splinting helps in accomplishing stability by redistributing the functional and parafunctional forces. There are various materials that have been used for periodontal splinting. Fiber-reinforced composite, composite resin, and metal-reinforced composite are often used as splinting materials for periodontally compromised teeth. In our study, a comparison was done among these materials for their ability to distribute the stresses at different bone levels in mobile lower incisors splinted together with canines. Materials and Methods: Five patients of age group 25-50 years with Grade 2 and 3 mobile incisors having 40% or more bone loss and firm canines with optimal bone support were selected. From the computed tomography scan of each patient, three models were developed demonstrating splinting of mandibular incisors and canines with metal-reinforced composite, fiber-reinforced composite, and composite resin. So in total, 15 models were developed and each one of them was subjected to vertical and transverse loads of 150 N. Pattern of stress distribution was observed in these models using three-dimensional finite element analysis. Results: After splinting, the stress on the canine increased when bone levels around incisors decreased while stress on incisors reduced. Conclusion: Tested splinting materials were successful in stress distribution, and metal-reinforced composite was found to be better than the other splinting materials. © 2019 Indian Journal of Dental Research.
Swift catalytic reduction of hazardous pollutants by new generation microgels
(Royal Society of Chemistry, 2022) Vinai Kumar Singh; Krishna Kumar; Nishant Singh; Rudramani Tiwari; S. Krishnamoorthi
In this manuscript, we report for the first time a new generation microgel synthesis without using any divinyl functionalized cross-linker. A new generation less crosslinked microgel structure has been achieved by optimizing the amount of N-hydroxy methyl acrylamide (NHMA) and using a fixed amount of styrene (St), acrylic acid (AA) and N-vinyl pyrrolidone (NVP) via a free radical emulsion solution polymerization technique. Poly(NHMA) works as a hydrophilic as well as a crosslinking agent. Furthermore, microgels have been upgraded into a composite by incorporation of Ag nanoparticles for catalytic reduction applications. Microgels and their composites have been characterized by EDAX, FT-IR, particle size analyzer, SEM, TEM, TGA, UV-vis spectroscopy and XRD. Methylene blue (MB) dye and p-nitrophenol (PNP) were chosen as model hazardous pollutants for catalytic reduction applications. Microgels efficiently adsorb both pollutants over the surface and microgel_Ag composites dramatically reduced both pollutants in the non-toxic form at room temperature by using smaller doses of NaBH4. © The Royal Society of Chemistry.