Browsing by Author "Prins Kumar Rao"

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Electrochemical capacitance and hydrogen adsorption behavior of activated carbon derived from cattail fiber
(John Wiley and Sons Inc, 2024) Ramesh Achayalingam; Sourabh Basu; Prins Kumar Rao; Jyotsana Pandey; Nivetha Selvaraj; Jayachitra Selvam; M. Sterlin Leo Hudson
In this paper, we have reported the synthesis of activated carbon (AC) from biomass cattail fiber through hydrothermal carbonization, followed by chemical activation, and its electrochemical capacitance and hydrogen storage properties. The AC exhibits a Brunauer-Emmett-Teller (BET) surface area (SBET) of 1597.5 m2g−1, determined from the low-pressure N2 adsorption isotherm at 77 K using a BET-multipoint plot. The AC sample shows a reversible hydrogen adsorption capacity of 0.25 wt.% H2 (1.25 mmol H2 g−1) at 293 K and 74 atm. The capacitance performance of AC was investigated with various conductive additives such as carbon nanotubes (CNTs), carbon black (CB), and reduced graphene-oxide (rGO). From galvanostatic charge discharge (GCD) and cyclic voltammetry (CV) measurements, the as-derived AC with polymer binder exhibits a specific capacitance (Cs) of 245.2 F g−1 at 0.2 A g−1 and 158.1 F g−1 at 5 mV s−1. Among the investigated conductive additives, AC with CNTs in KOH electrolyte exhibit highest Cs of 326 F g−1 at 0.2 A g−1 and 173 F g−1 at 5 mV s−1. Furthermore, the symmetrical two-electrode device fabricated using AC with CNTs (as a conductive additive) in 1 M aq. Na2SO4 electrolyte shows a Cs of 97.2 F g−1 at 0.1 A g−1. The energy and power densities of the two-electrode device were observed to be 28 kW kg−1 and 2.64 Wh kg−1, respectively. © 2024 John Wiley & Sons Ltd.