Browsing by Author "Xing Diao"

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Atmospheric phosphorus and its geochemical cycling: Fundamentals, progress, and perspectives
(Elsevier B.V., 2023) Xing Diao; David Widory; Kirpa Ram; Lekhendra Tripathee; Srinivas Bikkina; Kimitaka Kawamura; Shaopeng Gao; Xin Wan; Guangming Wu; Qiaomin Pei; Xiaoping Wang; Zhiyuan Cong
Phosphorus (P) is an essential macronutrient for all organisms that can be redistributed between terrestrial and oceanic systems via atmospheric emission, transport, transformation, and deposition. Moreover, since natural P mobilization from the lithosphere to ecosystems is a relatively slow process, the role of atmospheric P seems to play an important role in its cycling. This paper provides a comprehensive review of the analytical methods used for characterizing atmospheric P species and the methods used for identifying P sources (e.g., oxygen stable isotope compositions of phosphate, δ18OP) discussing their respective suitability, advantages, and limitations. While at a regional scale δ18OP of atmospheric P are generally source-specific, at a more global scale these isotope compositions tend to overlap between sources, rendering their tracer potential more difficult. Furthermore, various sources of atmospheric P and their fluxes are compiled, and the potential uncertainties in the estimates of their respective contributions are reviewed, which suggest that more model inter-comparations, parameter optimizations, and field observations are still needed. Moreover, we summarize the long-range transport process controlling P atmospheric dispersion at various scales (focusing on dust and biomass burning). In addition, the transformation mechanism, especially acid dissolution, that modifies the P cycle during its residence time in the atmosphere is depicted. Finally, we propose that land cover may be a potential key control to the atmospheric P deposition rate based on the critical analysis of previously published rates. This review allows us to ultimately propose key recommendations for fostering future research on P geochemical cycling. © 2023
Attributing Atmospheric Phosphorus in the Himalayas: Biomass Burning vs Mineral Dust
(American Chemical Society, 2024) Xing Diao; David Widory; Kirpa Ram; Enzai Du; Xin Wan; Shaopeng Gao; Qiaomin Pei; Guangming Wu; Shichang Kang; Zhong Wang; Xiaoping Wang; Zhiyuan Cong
Atmospheric phosphorus is a vital nutrient for ecosystems whose sources and fate are still debated in the fragile Himalayan region, hindering our comprehension of its local ecological impact. This study provides novel insights into atmospheric phosphorus based on the study of total suspended particulate matter at the Qomolangma station. Contrary to the prevailing assumptions, we show that biomass burning (BB), not mineral dust, dominates total dissolved phosphorus (TDP, bioavailable) deposition in this arid region, especially during spring. While total phosphorus is mainly derived from dust (77% annually), TDP is largely affected by the transport of regional biomass-burning plumes from South Asia. During BB pollution episodes, TDP causing springtime TDP fluxes alone accounts for 43% of the annual budget. This suggests that BB outweighs dust in supplying bioavailable phosphorus, a critical nutrient, required to sustain Himalayas’ ecological functions. Overall, this first-hand field evidence refines the regional and global phosphorus budget by demonstrating that BB emission, while still unrecognized, is a significant source of P, even in the remote mountains of the Himalayas. It also reveals the heterogeneity of atmospheric phosphorus deposition in that region, which will help predict changes in the impacted ecosystems as the deposition patterns vary. © 2023 American Chemical Society.
Nitrogen aerosols in New Delhi, India: Speciation, formation, and sources
(Elsevier Ltd, 2024) Qiaomin Pei; Xin Wan; David Widory; Kirpa Ram; Bhupesh Adhikary; Guangming Wu; Xing Diao; Hemraj Bhattarai; Yan-Lin Zhang; Mark Loewen; Zhiyuan Cong
Delhi, the capital city of India, experiences severe air pollution and suffers from its adverse effects on human health and ecosystems. This pollution is characterized by high levels of pollutants, including atmospheric nitrogen in both the gaseous and particulate phases. However, there is a lack of simultaneous measurement of chemical composition, tracers and 15N data in aerosols to understand the influence of different sources on N aerosols over Delhi. Here, we measured total nitrogen (TN), water-soluble total nitrogen (WSTN), water-soluble inorganic nitrogen (WSIN), and N stable isotope compositions (δ15N) in PM2.5 samples covering the post-monsoon, winter, and summer periods of the year 2018–19. NH4+-N was the major N species, accounting for an average 58% of TN and 68% of WSIN. The temporal variations of TN, WSTN, NH4+-N, NO3−-N, and WSON showed peaks in the post-monsoon and winter seasons, exhibiting seasonality similar to PM2.5 and levoglucosan (a biomass-burning tracer) indicating their co-genetic sources. Based on the correlation analysis between δ15N and N-species, we identified two distinct secondary chemical processes: i) in an NH4+-poor atmosphere, the gas-to-particle (NH3 → NH4+) conversion and subsequent formation of NH4HSO4 was the main process controlling the 15N and nitrogen enrichments in PM2.5; whereas ii) under NH4+-rich conditions, the formation and dissociation of NH4NO3 dominated. The coupled HYSPLIT and PSCF analyses highlighted the transport and contributions of open biomass burning emissions under a northwesterly atmospheric flow during post-monsoon as well as from local biomass combustion (from cooking and heating) during winter in the city and its vicinity. Our results suggested that i) both NH4+-N and NO3−-N were mainly impacted by biomass combustion during post-monsoon and winter seasons, and ii) NO3−-N resulted of dust transport from the Thar Desert in the summer season, but not NH4+-N. Finally, we recommend that future research focuses on the study of the seasonality of atmospheric nitrogen composition using 15N data from their different sources to design tailor-made measures and policies regarding the different potential sources, combining them within a comprehensive framework to ultimately improve air quality and the living environment in Delhi. © 2023