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Scholarly Publications
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https://dl.bhu.ac.in/bhuir/handle/123456789/16335
This community showcases the academic contributions of faculty and researchers at Banaras Hindu University (BHU) and provides a year-wise compilation of publications across disciplines. Institutional Repository BHU
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Publication
Article
Metal ion mediated imprinting for electrochemical enantioselective sensing of l-histidine at trace level
(
2011
)
Bhim Bali Prasad
;
Deepak Kumar
;
Rashmi Madhuri
;
Mahavir Prasad Tiwari
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Enantioselective trace level sensing of l-histidine (limit of detection, 1.980ngmL -1, S/N=3) was feasible with the use of a typical, reproducible, and rugged complex imprinted polymer-based pencil graphite electrode, in aqueous samples. In the present instance, the Cu 2+ ion-mediated imprinting of l-histidine in an molecularly imprinted polymer motif actually helped upbringing electrocatalytic activity to respond an enhanced differential pulse anodic stripping voltammetric oxidation peak of l-histidine, without any cross-reactivity and false-positive, in real samples. The proposed sensor could be considered suitable for the practical applications in biomarking histedinemia, a disease associated with l-histidine metabolic disorders, in clinical settings. © 2011 Elsevier B.V.
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