Title: Heteroleptic half-sandwich Ru(II), Rh(III) and Ir(III) complexes based on 5-ferrocenyldipyrromethene
| dc.contributor.author | Mahendra Yadav | |
| dc.contributor.author | Ashish Kumar Singh | |
| dc.contributor.author | Daya Shankar Pandey | |
| dc.date.accessioned | 2026-02-07T05:28:20Z | |
| dc.date.issued | 2011 | |
| dc.description.abstract | The synthesis and characterization of heteroleptic complexes with the formulations [(η6-arene)RuCl(fcdpm)] (η6-arene = C6H6, C10H14) and [(η5-C5Me5)MCl(fcdpm)] (M = Rh, Ir; fcdpm = 5-ferrocenyldipyrromethene) have been reported. All the complexes have been characterized by elemental analyses, IR, 1H NMR and electronic spectral studies. Structures of [(η6-C6H 6)RuCl(fcdpm)] and [(η6-C10H 14)RuCl(fcdpm)] have been determined crystallographically. Chelating monoanionic linkage of fcdpm to the respective metal centres has been supported by spectral and structural studies. Further, reactivity of the representative complex [(η6-C10H14)RuCl(fcdpm)] with ammonium thiocyanate (NH4SCN) and triphenylphosphine (PPh 3) have been examined. © 2010 Elsevier Ltd. All rights reserved. | |
| dc.identifier.doi | 10.1016/j.jorganchem.2010.09.070 | |
| dc.identifier.issn | 0022328X | |
| dc.identifier.uri | https://doi.org/10.1016/j.jorganchem.2010.09.070 | |
| dc.identifier.uri | https://dl.bhu.ac.in/bhuir/handle/123456789/23116 | |
| dc.subject | 5-Ferrocenyl-dipyrromethene | |
| dc.subject | Iridium(III) | |
| dc.subject | Piano-stool complexes | |
| dc.subject | Rhodium(III) | |
| dc.subject | Ruthenium(II) | |
| dc.title | Heteroleptic half-sandwich Ru(II), Rh(III) and Ir(III) complexes based on 5-ferrocenyldipyrromethene | |
| dc.type | Publication | |
| dspace.entity.type | Article |