Effective removal of fluoride from water by coconut husk activated carbon in fixed bed column: Experimental and breakthrough curves analysis

Abstract

The bio-waste coconut husk was converted into activated carbon through merely treating with KOH and thus obtained activated carbon was characterized by XRD, TGA, SEM and TEM analysis. The prepared activated carbon having very high surface area (1448 m2/g) was utilized as an adsorbent for the removal of fluoride (F-) from water. Fluoride adsorption experiments were performed on the laboratory-scale column at different bed height, flow rates, and F- concentrations to explore the potential of prepared adsorbent and it was found to be very efficient adsorbent as it showed high adsorption capacity 6.5 mg/g at pH 5, F- concentration 10 mg/L and adsorbent dose 1.4 g/L. Various breakthrough models i.e. Bed Depth Service Time (BDST), Thomas and Yoon–Nelson were applied on breakthrough data to analyze the breakthrough curves. The high R2 values obtained for the BDST model revealed its validity for this adsorption system. Breakthrough curves were successfully analyzed and described by both Thomas and Yoon–Nelson models. The exhausted adsorbent was efficiently regenerated with the 10% NaOH solution and regenerated adsorbent showed remarkable uptake capacity with a slight reduction in adsorption performance up to the 3 cycles. Life factor calculation indicated that adsorbent bed would have sufficient bed capacity up to 8.3 cycles to avoid breakthrough at time t = 0 and the bed would be completely exhausted after 9.0 cycles. © 2018