Enhanced piezocatalytic degradation of mixed organic dyes using BaTiO3–MoS2 heterostructure nanocomposites: A mechanistic investigation

Abstract

Piezocatalysis garners significant interest as a potential solution to environmental issues, specifically regarding dye pollutants. Nonetheless, the main obstacle in the piezoelectric efficiency of materials for eliminating organic pollutants from water has been the recombination of charge carriers. Here we report on the fabrication of a piezoelectric nanocomposite of BaTiO3 (BT) Nanoparticles and MoS2 (MS) Nanosheets for the enhanced piezocatalytic degradation of dye pollutants. The sample with 1.0 wt % MoS2 content (BT/MS1) demonstrates greater efficacy compared to both 2.0 wt % MoS2 (BT/MS2) and BaTiO3 (BT) alone in degrading Rhodamine B (Rh B) and Methyl Orange (MO). Specifically, BT/MS1 exhibits 1.84- and 2.8-times enhanced performance for Rh B and MO degradation respectively, in comparison to BT alone. It is demonstrated that the charge transfer system at the interface of BT and MS effectively lowers the recombination of electron-hole (e‒- h+) pairs, generated during piezocatalysis thereby enhancing the degradation. The composite sample was further used for the successful degradation of a mixture of dyes. This study introduces a novel approach to enhance catalysis by hybrid composite in piezoelectric materials. © 2024 Elsevier Ltd