The chemistry of cadmium-thiocarboxylate derivatives: Synthesis, structural features, and application as single source precursors for ternary sulfides

Abstract

Novel heterobimetallic complexes [(PPh3)2Cu(μ- SCOPh)2Cd(SCOPh)] (2a), [(PPh3)2Cu(μ-SCOth) 2Cd(SCOth)] (2b), [(PPh3)2Ag(μ-SCOth) 2Cd(SCOth)] (3a), [(PPh3)2Ag(μ-SCOth) 2Cd(H2O)(SCOth)] (3b), [(PPh3) 2Ag(μ-SCOPh)2Cd(SCOPh)] (3c), and a bimetallic complex [PPh3Cd(μ-SCOth)SCOth]2•CH2Cl 2 (5) (th = thiophene) were prepared and characterized by single crystal X-ray diffraction analysis. A coordination polymer [Cd(SCOPh) 2]n (4) has also been characterized structurally that exhibited metal-like electrical conductivity. The heterobimetallic complexes on pyrolyzing under controlled conditions yielded ternary sulfides of composition CuCd7S8, CuCd10S11, Ag 2Cd8S9, and Ag2Cd5S 6, which have been characterized by SEM-EDX and X-ray diffractometry. Photophysical properties and electrical conductivities of the sulfides have also been studied. © 2011 American Chemical Society.