Title: Synthesis of mono- and bi-metallic dithiocarboxylate-alkyne complexes from sunlight driven insertion reaction and their antibacterial activity
| dc.contributor.author | Sumanta K. Patel | |
| dc.contributor.author | Vijaylakshmi Tirkey | |
| dc.contributor.author | Sasmita Mishra | |
| dc.contributor.author | Hirak R. Dash | |
| dc.contributor.author | Surajit Das | |
| dc.contributor.author | Madhulata Shukla | |
| dc.contributor.author | Satyen Saha | |
| dc.contributor.author | Shaikh M. Mobin | |
| dc.contributor.author | Saurav Chatterjee | |
| dc.date.accessioned | 2026-02-07T06:04:31Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | Sunlight driven synthesis, characterization and antibacterial evaluation of cyclopentadienyl based metal-dithiocarboxylate alkyne complexes, [LM(CO) n(η2-S2C)CCR], [{L = η5- C5H5, M = W, R = (η5-C5H 4)Fe(η5-C5H5), n = 2}; {L = η5-C5H5, M = W, R = -C(CH 3)CH2, n = 2}; {L = η5-C5H 5, M = Mo, R = -C(CH3)CH2, n = 2}; {L = η5-C5Me5, M = Fe, R = Ph, n = 1}] (5-8) have been carried out. Reactivity of metal-dithiocarboxylate alkyne complexes towards dicobaltoctacarbonyl were studied to obtain a trimetallic dithiocarboxylate complex (9-11). Structural characterizations of 7 and 8 have been carried out crystallographically and DFT calculation was performed on compound 8 to understand the electronic properties of the complex. © 2013 Elsevier B.V. All rights reserved. | |
| dc.identifier.doi | 10.1016/j.jorganchem.2013.09.018 | |
| dc.identifier.issn | 0022328X | |
| dc.identifier.uri | https://doi.org/10.1016/j.jorganchem.2013.09.018 | |
| dc.identifier.uri | https://dl.bhu.ac.in/bhuir/handle/123456789/27164 | |
| dc.subject | Antibacterial | |
| dc.subject | Bio-organometallic | |
| dc.subject | Dithiocarboxylate | |
| dc.subject | Sunlight | |
| dc.title | Synthesis of mono- and bi-metallic dithiocarboxylate-alkyne complexes from sunlight driven insertion reaction and their antibacterial activity | |
| dc.type | Publication | |
| dspace.entity.type | Article |