Studies of inter/intramolecular weak interactions with CH⋯S and S⋯arene interaction in symmetrical and dissymmetrical models

Abstract

Evidences have proved the versatile role of sulfur atom in supramolecular chemistry.1 Presence of S atom in the molecule usually results in the specific structural properties of molecules. In the present study, S⋯arene, N⋯arene, CH⋯π, CH⋯ S and CH⋯N type of weak interactions stabilize the conformation and self assembly of symmetrical as well as dissymmetrical molecules.