Preparation, characterization and molecular electrical conductivity of an ion-pair complex and mixed-metallic coordination polymers derived from maleonitriledithiolate

Singh, NanhaiSinha, Rohit Kumar2025-03-042025-03-04200313877003https://dl.bhu.ac.in/ir/handle/123456789/88452An ion-pair complex [Cd(en)3]22+ [Ag4(mnt)4]4- and three mixed metallic coordination polymers MNi(mnt)2 [M = Pd(II), 2Ag(I) or Hg(II); mnt2- = maleonitriledithiolate] have been prepared and characterized using IR, UV-Visible and conductivity techniques. All of the complexes exhibit pressed pellet σrt ≃ 10-5 S cm-1 and show electrical behaviour of semiconductors over 303-393 K range. © 2002 Elsevier Science B.V. All rights reserved.Mixed-metallic maleonitriledithiolate complexesSemiconductorsSolid phase conductivityUV-Visible spectraPreparation, characterization and molecular electrical conductivity of an ion-pair complex and mixed-metallic coordination polymers derived from maleonitriledithiolateArticlehttps://doi.org/10.1016/S1387-7003(02)00666-4