Browsing by Author "Jana S."
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Item Emerging concern of nano-pollution in agro-ecosystem: Flip side of nanotechnology(Elsevier Masson s.r.l., 2024) Moulick D.; Majumdar A.; Choudhury A.; Das A.; Chowardhara B.; Pattnaik B.K.; Dash G.K.; Murmu K.; Bhutia K.L.; Upadhyay M.K.; Yadav P.; Dubey P.K.; Nath R.; Murmu S.; Jana S.; Sarkar S.; Garai S.; Ghosh D.; Mondal M.; Chandra Santra S.; Choudhury S.; Brahmachari K.; Hossain A.Nanomaterials (NMs) have proven to be a game-changer in agriculture, showcasing their potential to boost plant growth and safeguarding crops. The agricultural sector has widely adopted NMs, benefiting from their small size, high surface area, and optical properties to augment crop productivity and provide protection against various stressors. This is attributed to their unique characteristics, contributing to their widespread use in agriculture. Human exposure from various components of agro-environmental sectors (soil, crops) NMs residues are likely to upsurge with exposure paths may stimulates bioaccumulation in food chain. With the aim to achieve sustainability, nanotechnology (NTs) do exhibit its potentials in various domains of agriculture also have its flip side too. In this review article we have opted a fusion approach using bibliometric based analysis of global research trend followed by a holistic assessment of pros and cons i.e. toxicological aspect too. Moreover, we have also tried to analyse the current scenario of policy associated with the application of NMs in agro-environment. � 2024 Elsevier Masson SASItem Engineered Ni�Fe prussian blue analogue nanocubes and their transformation into nanocages and mixed oxide for applications as bifunctional electrocatalyst(Elsevier Ltd, 2024) Pal S.; Jana S.; Singh D.K.; Ganesan V.; Azad U.P.; Prakash R.3D nanostructured Prussian blue analogues (PBA) are promising candidates in the family of metal-organic frameworks (MOFs) for applications as bifunctional electrocatalysts due to their open framework structures, high specific surface areas and variable metal active sites. Due to their facile synthesis approach and unique framework structures, these nanostructures can be easily transformed into different structures/materials having different compositions. Herein, we have synthesized Ni�Fe Prussian blue analogue nanocubes (NiFe-PBA-NC) via a simple precipitation method and converted them into Ni�Fe Prussian blue analogue nanocages (NiFe-PBA-NG) and porous mixed metal oxide (NiFe-oxide). For the conversion of nanocubes to nanocages a very controlled etching process is carried out by using an ammonia solution while for the formation of porous mixed metal oxide, nanocubes are annealed in the presence of air. The transformation of nanocubes to nanocages and mixed metal-oxide is thoroughly characterized by various spectroscopic and microscopic techniques and employed as a bifunctional electrocatalyst for oxygen evolution and oxygen reduction reactions (OER and ORR, respectively) in which NiFe-oxide proved to be the best bifunctional catalyst. This thorough and systematic study reveals the fundamentals of the structure-property co-relation towards engineering novel bifunctional electrocatalysts. � 2023 Hydrogen Energy Publications LLC