Publication:
Preparation, characterization and molecular electrical conductivity of an ion-pair complex and mixed-metallic coordination polymers derived from maleonitriledithiolate

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Date

2003

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Journal Title

Inorganic Chemistry Communications

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Research Projects

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Abstract

An ion-pair complex [Cd(en)3]22+ [Ag4(mnt)4]4- and three mixed metallic coordination polymers MNi(mnt)2 [M = Pd(II), 2Ag(I) or Hg(II); mnt2- = maleonitriledithiolate] have been prepared and characterized using IR, UV-Visible and conductivity techniques. All of the complexes exhibit pressed pellet σrt ≃ 10-5 S cm-1 and show electrical behaviour of semiconductors over 303-393 K range. © 2002 Elsevier Science B.V. All rights reserved.

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Keywords

Mixed-metallic maleonitriledithiolate complexes, Semiconductors, Solid phase conductivity, UV-Visible spectra

Citation

URI

https://dl.bhu.ac.in/ir/handle/123456789/88452

DOI

https://doi.org/10.1016/S1387-7003(02)00666-4

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2003