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A Cu(ii) mediated new desulfurization pathway involving elimination of ethylene sulfide

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dc.contributor.authorSareen, Neha
dc.contributor.authorSingh, Suryabhan
dc.contributor.authorBhattacharya, Subrato
dc.date.accessioned2025-03-03T05:27:04Z
dc.date.available2025-03-03T05:27:04Z
dc.date.issued2014
dc.description.abstractReaction of thiodiacetate anion (tda) with [Cu(TMEDA)(NO3) 2] (TMEDA = N,N,N′N′-tetramethyl ethylene-diamine) in a stoichiometric ratio afforded the complex {[Cu(TMEDA)(tda)]·(H 2TMEDA)(NO3)2·H2O} (1). When [Cu(TMEDA)(NO3)2] was added in excess, it yielded a μ-oxalato complex {[Cu2(TMEDA)2(μ-ox)(H 2O)2](NO3)2·2CH 3CN} (2). The reaction involves a facile room temperature desulfurization of the thiodiacetate moiety via elimination of ethylene sulfide (thiirane). © 2014 The Royal Society of Chemistry.
dc.identifier.doihttps://doi.org/10.1039/c3dt53395f
dc.identifier.issn14779234
dc.identifier.urihttps://dl.bhu.ac.in/ir/handle/123456789/77010
dc.titleA Cu(ii) mediated new desulfurization pathway involving elimination of ethylene sulfide
dc.typeArticle
dspace.entity.typePublication
journal.titleDalton Transactions
journalvolume.identifier.volume43

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