Publication: A new approach for nano-structuring of glassy selenium (g-Se) using silver nanoparticles (AgNPs) as precursor
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Date
2021
Authors
Journal Title
Materials Today Communications
Journal ISSN
Volume Title
Publisher
Elsevier Ltd
Abstract
Various routes have been proposed for the synthesis of chalcogen based nanostructured materials but the search of conventional and cost-effective method for the nanostructuring of chalcogenides is an ongoing research activity. This unique work reports the synthesis and the characterization of a novel kind of glassy nanocomposite material belonging to the nano-structuring of g-Se with the help of silver nanoparticles. The local structure is analyzed with the help of X-ray diffraction, Scanning electron microscopy, Raman spectroscopy, and Differential Scanning Calorimetry. It was found that the addition of AgNPs in glassy Se creates fine nano-wires of trigonal Selenium (t-Se) in the glass matrix of g-Se. The electrical, mechanical, and thermal characterizations of the present glassy nanocomposite material have been done in terms of current-voltage characteristics, d.c. conductivity, micro-hardness, and kinetic parameters of glass/crystal phase transformation. A comparative analysis of present glassy composites with a conventional Ag containing glassy alloy (g-Se98Ag2) has also been done to understand the role of incorporation of silver nanoparticles over the normal silver powder. The detailed analysis shows that different physical properties [e.g., thermal stability, modulus of elasticity, micro-hardness, the threshold voltage (i.e., turn-on voltage for resistive switching), and d.c. conductivity] are enhanced more effectively when the nano-structuring of g-Se by using AgNPs is executed as compared to the routine way of alloying. � 2020 Elsevier Ltd
Description
Keywords
Glass, Glassy nanocomposite, Nano-particles, Nano-structuring