I2-Mediated Site-Selective C-H Functionalization: Access to p-Amino-Substituted Unsymmetrical Benzils and Quinoxalines from Sulfoxonium Ylides

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dc.contributor.authorSaini R.K.
dc.contributor.authorBorpatra P.J.
dc.contributor.authorChaubey T.N.
dc.contributor.authorPandey S.K.
dc.date.accessioned2025-01-13T07:05:47Z
dc.date.available2025-01-13T07:05:47Z
dc.date.issued2024
dc.description.abstractAn I2-mediated approach for selective C-H functionalization of unprotected aniline derivatives for synthesizing benzils and quinoxaline derivatives from sulfoxonium ylides has been described. Aniline derivatives and sulfoxonium ylides ornamented with different functional groups showed good compatibility. They afforded the corresponding products with moderate to high yields via a mild and simple procedure. Finally, we validated the practicality of this method by scaling up the reaction and further conversion of the synthesized derivatives into other valuable molecules. � 2024 American Chemical Society.
dc.identifier.doi10.1021/acs.joc.3c02975
dc.identifier.issn223263
dc.identifier.urihttps://dl.bhu.ac.in/ir/handle/123456789/2066
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.titleI2-Mediated Site-Selective C-H Functionalization: Access to p-Amino-Substituted Unsymmetrical Benzils and Quinoxalines from Sulfoxonium Ylides
dc.typeArticle
journal.titleJournal of Organic Chemistry
journalvolume.identifier.volume89

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