Electrochemical Hydroxylation of ?-Bromoacetophenones: Access to ?-Hydroxyacetophenones

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dc.contributor.authorSingh S.
dc.contributor.authorRay S.
dc.contributor.authorShukla G.
dc.contributor.authorSingh M.
dc.contributor.authorSingh M.S.
dc.date.accessioned2025-01-13T07:05:28Z
dc.date.available2025-01-13T07:05:28Z
dc.date.issued2024
dc.description.abstractHerein, a new method has been developed for the synthesis of various ?-hydroxyacetophenones via an electro-oxidation process. It involves electrocatalytic hydroxylation via debromination of C(sp3)?Br bond. Here, simultaneous breaking of carbon-bromine (C?Br) bond and formation of a new carbon-oxygen (C?O) bond has been achieved through electrolysis of H2O using binary mixture of water and DMSO. The protocol features easy performance, oxidant and base-free mild conditions and short reaction time. � 2024 Wiley-VCH GmbH.
dc.identifier.doi10.1002/adsc.202301395
dc.identifier.issn16154150
dc.identifier.urihttps://dl.bhu.ac.in/ir/handle/123456789/1964
dc.language.isoen
dc.publisherJohn Wiley and Sons Inc
dc.subjectBromoacetophenones
dc.subjectElectrolysis
dc.subjectHydroxylation
dc.subjectMetal-free
dc.subjectOxidant-free
dc.titleElectrochemical Hydroxylation of ?-Bromoacetophenones: Access to ?-Hydroxyacetophenones
dc.typeArticle
journal.titleAdvanced Synthesis and Catalysis
journalvolume.identifier.volume366

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