Synthesis, Characterization and Electrical conductivities of the Complexes of Nickel(II), Copper(II) and Zinc(II) with 2,5-diamino-3,6-dichloro-1,4-benzoquinone
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Date
2024
Authors
Journal Title
Research Journal of Chemistry and Environment
Journal ISSN
Volume Title
Publisher
World Researchers Associations
Abstract
Complexes of the type [M(dadb)] (M = Ni(II), Cu(II) and Zn(II)) with ligand 2,5-diamino-3,6-dichloro-1,4-benzoquinone (dadb) have been synthesized and characterized by microanalysis, magnectic susceptibility, electronic, IR, ESR spectroscopy techniques, thermogravimetric analysis (TG), differential thermal analysis (DTA), X-ray powder diffraction (XRD) and solid phase conductivity measurements. The room temperature ESR spectra of Cu(II) complex yield <g >values, characteristics of square planar geometry. The solid state electrical conductivities of the complexes increase as the temperature increases from 311-383 K, with a band gap of 0.11- 0.21 eV, indicating their semiconducting behaviour. � 2024 World Researchers Associations. All rights reserved.
Description
Keywords
complexes, Conductivity, Copper, DADB, Nickel, Zinc