Synthesis, Characterization and Electrical conductivities of the Complexes of Nickel(II), Copper(II) and Zinc(II) with 2,5-diamino-3,6-dichloro-1,4-benzoquinone

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dc.contributor.authorKushwaha A.
dc.contributor.authorSmriti D.
dc.contributor.authorPrasad R.L.
dc.date.accessioned2025-01-13T07:05:47Z
dc.date.available2025-01-13T07:05:47Z
dc.date.issued2024
dc.description.abstractComplexes of the type [M(dadb)] (M = Ni(II), Cu(II) and Zn(II)) with ligand 2,5-diamino-3,6-dichloro-1,4-benzoquinone (dadb) have been synthesized and characterized by microanalysis, magnectic susceptibility, electronic, IR, ESR spectroscopy techniques, thermogravimetric analysis (TG), differential thermal analysis (DTA), X-ray powder diffraction (XRD) and solid phase conductivity measurements. The room temperature ESR spectra of Cu(II) complex yield <g >values, characteristics of square planar geometry. The solid state electrical conductivities of the complexes increase as the temperature increases from 311-383 K, with a band gap of 0.11- 0.21 eV, indicating their semiconducting behaviour. � 2024 World Researchers Associations. All rights reserved.
dc.identifier.doi10.25303/285rjce024029
dc.identifier.issn9720626
dc.identifier.urihttps://dl.bhu.ac.in/ir/handle/123456789/2065
dc.language.isoen
dc.publisherWorld Researchers Associations
dc.subjectcomplexes
dc.subjectConductivity
dc.subjectCopper
dc.subjectDADB
dc.subjectNickel
dc.subjectZinc
dc.titleSynthesis, Characterization and Electrical conductivities of the Complexes of Nickel(II), Copper(II) and Zinc(II) with 2,5-diamino-3,6-dichloro-1,4-benzoquinone
dc.typeArticle
journal.titleResearch Journal of Chemistry and Environment
journalvolume.identifier.volume28

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